#EESpublishes: Prof #BlaszczakBoxe of @GC_CUNY on the #Martian #ozone profile

Professor Christopher Blaszczak-Boxe of the CUNY Grad Center and City College co-authored a paper in ICARUS entitled

A detailed pathway analysis of the chemical reaction system generating the Martian vertical ozone profile.


•Determination of all significant O3 producing and consuming pathways and quantification of their contributions in the Martian atmosphere with help of an automated computer algorithm.
•O3 production results from CO2 and O2 photolysis.
•O3 is consumed by catalytic cycles involving HOx (=H+OH+HO2).
•The Martian atmosphere can be divided into two chemically distinct re- gions according to the O(3P):O3 ratio.
•Vertical transport of O(3P) from upper layers downwards into the O3 layer at around 50 km altitude provides an additional source of Ox (=O+O3), which is pivotal to the formation of the Martian O3 volume mixing ratio maximum.


Atmospheric chemical composition is crucial in determining a planet’s atmospheric structure, stability, and evolution. Attaining a quantitative understanding of the essential chemical mechanisms governing atmospheric composition is nontrivial due to complex interactions between chemical species. Trace species, for example, can participate in catalytic cycles – affecting the abundance of major and other trace gas species. Specifically, for Mars, such cycles dictate the abundance of its primary atmospheric constituent, carbon dioxide (CO2), but also for one of its trace gases, ozone (O3). The identification of chemical pathways/cycles by hand is extremely demanding; hence, the application of numerical methods, such as the Pathway Analysis Program (PAP), is crucial to analyze and quantitatively exemplify chemical reaction networks. Here, we carry out the first automated quantitative chemical pathway analysis of Mars’ atmosphere with respect to O3. PAP was applied to JPL/Caltech’s 1-D updated photochemical Mars model’s output data. We determine all significant chemical pathways and their contribution to O3 production and consumption (up to 80 km) in order to investigate the mechanisms causing the characteristic shape of the O3 volume mixing ratio profile, i.e. a ground layer maximum and an ozone layer at ∼ 50 km. These pathways explain why an O3 layer is present, why it is located at that particular altitude and what the different processes forming the near-surface and middle atmosphere O3 maxima are. Furthermore, we show that the Martian atmosphere can be divided into two chemically distinct regions according to the O(3P):O3 ratio. In the lower region (below approximately 24 km altitude) O3 is the most abundant Ox ( = O3 + O(3P)) species. In the upper region (above approximately 24 km altitude), where the O3 layer is located, O(3P) is the most abundant Ox species. Earlier results concerning the formation of O3 on Mars can now be explained with the help of chemical pathways leading to a better understanding of the vertical O3 profile.